The Effect of Different Concentration of Silica Nanoparticles on the Rheology Behavior of ‎a Acrylamide-based Terpolymer Synthesized via In-situ Inverse Emulsion
Paper ID : 1576-ICNS
Authors:
Saeed Ghaderi1, ali babaie2, Ahmadreza Karimi3, Seyyedarash Haddadi4, Ahmad Ramazani S.A. *5
1Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
2chemical engineering at sharif university of technology
3Chemical and Petroleum Engineering Department, Faculty of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, Iran
4School of Engineering, University of British Columbia, Kelowna V1V 1V7, Canada
5Sharif University of Technology
Abstract:
Water-soluble acrylamide-modified terpolymer nanocomposites modified with hydrophilic groups of maleic ‎anhydride and hydrophobic units of styrene, containing silica nanoparticles were synthesized using in-situ ‎polymerization and their rheological properties were studied. The formation of terpolymer and the incorporation ‎of silica nanoparticles into the structure of the terpolymer was studied by Fourier Transform Infrared ‎Spectroscopy (FT-IR) and the microstructure and size of the terpolymer and silica nanoparticles were ‎investigated by field emission scanning electron microscopy (FE-SEM). The rheological properties including ‎shear viscosity in different concentration of nanoparticle and different temperatures of the terpolymer solutions ‎and terpolymer containing silica nanoparticles solutions at different temperatures were studied using RMS ‎dynamic spectroscopy. The obtained results from RMS showed that the nanocomposites are resistance against ‎increasing temperature and by increasing the concentration of nanoparticles from 0.5 % wt. to 1.5 % wt., the ‎shear viscosities increase noticeably. These interesting temperature resistance behavior concludes that such ‎nanocomposites can practically be used in harsh conditions with high temperatures.‎
Keywords:
Nanocomposite, Acrylamide terpolymer, Rheological modifier, Salt-resistance‎
Status : Abstract Accepted (Poster Presentation)