Synthesis and Characterization of a Novel Cubic Ordered Mesoporous Polymer Containing Imidazolium Ionic liquid via Nanocasting Method |
Paper ID : 1519-ICNS |
Authors: |
Babak Karimi1, Anahita Safiyan *2, Fariborz Mansouri3 1Department of Chemistry, IASBS 2chemistry department, Dr Karimi, IASBS, Zanjan, Iran 3depatment of chemistry, organic chemistry, IASBS, |
Abstract: |
Abstract: New imidazolyl-functionalized ordered mesoporous cross-linked polymer with 3D cubic structure was prepared by the copolymerization of the ionic liquid 3-benzyl-1-vinyl-1-H-imidazolium bromide with divinylbenzene as the cross-linker and azobisisobutyronitrile as the radical initiator in the presence of O-silylated KIT-6 as the hard template. The material was characterized using Fourier-transform infrared spectroscopy (FT-IR), thermo-gravimetric analysis (TGA), N2 sorption analysis, transmission electron microscopy (TEM) and elemental analysis (CHN). The material demonstrated a combination of exciting features such as high thermal decomposition temperature, high surface area, cubic mesoporous connectivity, available pore system and highly ionic density in the channels at the same time. |
Keywords: |
Keywords: Ionic Liquid, Nanocasting Method, Mesoporous Polymer. |
Status : Abstract Accepted (Poster Presentation) |